The Multi-Analytical Characterization of Calcium Oxalate Phytolith Crystals from Grapevine after Treatment with Calcination
نویسندگان
چکیده
Calcium oxalate phytoliths are one of the most prominent types Ca speciation in plant kingdom, and they store extensive amounts carbon crystalline form. were investigated root, trunk, bark Vitis vinifera Chasselas from a vineyard Alsace, France. A multi-analytical approach was used, which included SEM coupled with EDX spectroscopy, XRD, XRF, TGA, 13C-NMR spectroscopy. These techniques revealed that composed calcium monohydrate (whewellite). The whewellite crystals exhibited mostly equant or short-prismatic habits all three studied grapevine parts, but bipyramidal also occurred. Raphide only observed where abundant. Instead using wet chemical procedures to extract mineral components organic parts biomass, thermal treatment via calcination chosen. suitable temperature determined through TGA experiments. biomass samples at 250 °C enhanced residual chars. treatment, however, affected appearance by producing surfaces displayed macroporosity creating fractures. For both 300 350 °C, lost molecule monoxide form carbonate, modifications original crystal more pronounced than those after °C.
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ژورنال
عنوان ژورنال: Crystals
سال: 2023
ISSN: ['2073-4352']
DOI: https://doi.org/10.3390/cryst13060967